Deductive reasoning (or argument) was first distinguished from Inductive reasoning by Aristotle. He defined the difference between the two by the direction of logical inference: deduction moved from universal (or more clearly known) propositions, to particular (less clearly known ones), while he defined induction as the inference from particular claims to universal ones.
In contemporary Logic we define the difference based on the logical status of the conclusion: deductive arguments yield necessary conclusions, while inductive arguments yield probable conclusions.
The success, and therefore the evaluation, of deduction is dependent on two distinct factors:
If a deductive argument is valid AND has all true premises, it is called a sound argument.
For example:
Valid -
All dogs are cats.
Kato is a dog.
Therefore, Kato is a cat.
If we assume the truth of premises one and two the conclusion MUST follow (it could not fail to be true). So, this argument is valid (it is structured correctly). However, since the first premise is false, this argument is unsound.
Sound -
All dogs are mammals.
Kato is a dog.
Therefore, Kato is a mammal.
The structure of this argument is identical to the first argument, so it is obviously valid. And, in this case the first premise is also true, so this argument would be called sound.